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Authenticity Assessment from Sesame Seeds to Oil and Sesame Products of Various Origin by Differential Scanning Calorimetry
The aim of this study was to conduct thermal characterization of sesame seeds and oils from various geographical origins (Ethiopia, India, Nigeria, Sudan, Turkey), different method of extraction (hexane and cold-pressing), and different types of derived products (halva and tahini). Thermal characterization was investigated using differential scanning calorimetry (DSC), which showed that origin of the seeds has no influence on the melting profile of sesame oil (peak temperature and enthalpy). Method of extraction (hexane and cold-pressing) influenced the peak temperatures of the resulting oils (p ≤ 0.05). The addition of 20% of palm olein to pure sesame oil influenced the significant changes in thermodynamic parameters such as peak temperature (Tm2), which was lowered from −5.89 °C to −4.99 °C, peak half width (T1/2), elevated from 3.01 °C to 4.52 °C, and the percentage of first peak area (% peak 1) lowered from 87.9 to 73.2% (p ≤ 0.05). The PCA method enabled to distinguish authentic and adulterated sesame oils of various origins. There were no significant differences in thermal properties among the products (halva, tahini) and the authentic sesame oil (p > 0.05). The obtained results showed DSC feasibility to characterize sesame oil and sesame products in terms of authenticity.
DSC isothermal and non-isothermal assessment of thermo-oxidative stability of different cultivars of Camelina sativa L. seed oils
Increasing the Oxidative Stability of the Wafer Lipid Fraction with Fruit Extract during Storage
Confectionary products are increasingly popular among consumers. However, since they usually have a long shelf life (about 12 months), their oxidative stability during long-term storage becomes a significant issue. Thus, the aim of this study was to investigate the effect of addition of commercially available fruit extract on the oxidative stability of lipid fraction, extracted from wafers sheets stored 13 months at 18 °C. For this purpose, the oxidation induction times (OIT) were determined by using isothermal differential scanning calorimetry (DSC). Conjugated diene content (CD) and 2,2-diphenyl-1-pikrylhydrazyl (DPPH) antioxidant activity were also monitored. All results obtained showed that the fruit extract addition slowed down effectively the peroxidation process of lipid fraction of wafer sheets. The rate of OIT and CD changes during the first six months of storage were about two times lower for the sample with the extract (LWE) than for the control (LWS). The DPPH antioxidant activity of LWE was higher than for the LWS sample until the 8th month of storage. It was stated that fruit extract effectively enhanced the oxidative stability of lipid fraction of wafers up until the 10th month of storage. After this period, CD values increased significantly for LWS and LWE samples, while at the same time there were no significant differences in OIT and DPPH values between both samples (p > 0.05).