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An Analysis of the Physicochemical and Energy Parameters of Briquettes Manufactured from Sewage Sludge Mixtures and Selected Organic Additives
As a by-product of wastewater treatment, sewage sludge can be used for natural, agricultural, or energy purposes. One method of preparing sludge for management and use is solar drying. To intensify the drying process, natural additives can be used to alter the structure of the sludge and accelerate the evaporation of water. This research aimed to evaluate the influences of different organic additives in sewage sludge mixtures on the physicochemical and energy parameters of briquettes. This research was carried out without thermal boosting in a 4 × 2.5 × 2 m plastic tunnel. The tunnel was equipped with three drying stations and control and measuring equipment. In two test series, sludge additives in the form of straw and lignocellulosic materials, sawdust, bark, woodchips, and walnut shells, were used. Briquettes were made from the resulting mixtures and then subjected to physical and chemical analyses. This research showed high variability in the contents of trace elements, nitrogen, and sulphur in relation to an increase in the amount of sludge in the briquettes, which, for the briquettes made from sewage sludge, was nearly twice as high as for the briquettes made from the mixtures. The results of the flue gas analysis for the briquettes with sawdust and wood chip additives were very similar. The briquettes made from sewage sludge with lignocellulosic materials (bark and wood chips) had fuel properties similar to woody biomass, with a calorific value and heat of combustion of 15–16 MJ/kg. Fibrous additives (straw) significantly increased the strength parameters of the briquettes, by more than 50% of the value. The compositions and properties of the mixtures affected the following briquetting parameters: temperature and compressive force. The briquettes made from sewage sludge and additives can be classified according to ISO 21640 as SRFs (solid recovered fuels). In most of the results, the net calorific value (NCV) was 3 to 4; the chlorine content (CL) was 2 to 1; and the mercury content (Hg) was 1. The sewage sludge mixtures facilitated the agricultural and energy use of the briquettes.
Gases Emissions during Composting Process of Agri-Food Industry Waste
The vegetable production is an important part of agriculture sector in every country. In Poland, vegetables and fruits production covering the area of no more than 3% of agricultural land, is more than 36% of plant production and 14–15% of the whole agricultural production. The study aim was to determine the management possibilities of the selected waste from vegetable production in composting process. Laboratory tests were carried out using the bioreactor set-up with capacity of 165 dm3, respectively, for each chamber. The composting process has been tested for the following mixtures: K1—cabbage leaves, tomato dry leaves + manure and slurry additive; K2—cabbage leaves, solid fraction from biogas plant + manure and straw additive; K3—cabbage leaves, onion husk + straw additive. In all three composts the thermophilic phase occurred which indicates that the process ran correctly. In each chamber, the temperature exceeded 70 °C and its maximum value during the experiment was 77.5 °C for K2 compost. The article discusses changes in O2, CO2, NH3 and H2S emissions during composting. The carbon dioxide concentration in the exhausted gas from analyzed composts and the ratio with oxygen they testify to the decomposition of raw materials in the composting process. The results showed that the agri-food waste can be a proper substrate for composting production. Due to legal regulations and the increase in prices of mineral fertilizers, the development of the compost market should be expected.