Potential of Nanomaterials as Formaldehyde Scavengers in Wood-Based Composites
2025, Antov, Petar, Kawalerczyk, Jakub, Lee, Seng Hua, Lubis, Muhammad Adly Rahandi, Savov, Viktor, Antonov, Petar, Lubis, Muhammad Adly Rahandi, Lee, Seng Hua, Taghiyari, Hamid R.
The effect of pressing parameters and hardener content on the properties of plywood bonded with propylamine-UF adhesive
2024, Kawalerczyk, Jakub, Antov, Petar, Dziurka, Dorota, Mirski, Radosław, Lee, Seng Hua
The effect of the tree dieback process on the mechanical properties of pine (Pinus sylvestris L.) wood
2023, Malinowski, Zbigniew, Kawalerczyk, Jakub, Walkiewicz, Joanna, Dziurka, Dorota, Mirski, Radosław
As a result of the progressing climate changes, there is an increase in the volume of pine deadwood harvested each year from Polish forests. Its presence is an important part of the forest ecosystem; however, there are some indications that the material obtained from dying trees can be characterized by lower quality and properties. Taking into account the growing issue of tree dieback, the volume of pine wood annually harvested in Poland, and the importance of wooden products from an economic standpoint, preliminary research aimed at recognizing the process and its effect on the mechanical properties was conducted. Model trees in Brzeg Forest District were selected based on the crown defoliation. The properties of wood obtained from trees representing three different categories of soundness were determined according to the relevant standards. Based on the results of density, modulus of elasticity, bending strength, and compressive strength, it was found that there were statistically significant differences in wood quality depending on the condition of the tree. The results were particularly interesting in the case of compressing strength, where a healthy tree of lower density showed a similar strength to a dying tree with a much higher density.
Properties of sandwich boards with a core made of bio-composite particleboard containing wood particles and walnut shells
2024, Dukarska, Dorota, Grześkowiak, Wojciech, Kawalerczyk, Jakub, Klucewicz, Maciej, Florczak, Maciej, Góral, Błażej
AbstractThe aim of the research was to investigate the possibility of producing bio-composite particleboard with a density reduced to 500–550 kg/m3, containing 25% and 50% of walnut shells. In addition, the study also concerned the possibility of using these materials in sandwich systems. Based on the results, it was found that partial replacement of wood particles with ground shells leads to a significant reduction in the strength of the boards bonded with urea-formaldehyde (UF) resin. However, the implementation of a hybrid gluing method consisting of gluing wood particles with UF resin and walnut shells with 4,4′-methylenediphenyl isocyanate (pMDI) caused a significant improvement in the strength of the boards, especially for the variant with the highest shells content. Despite that, the manufactured materials still do not meet the requirements for furniture boards. The next step of the research has shown that these boards can perform well as a core layer in the sandwich boards covered with high-strength HDF boards. Moreover, it was found that increasing the share of walnut shells positively affected the dimensional stability of the resultant boards (thickness swelling and water absorption). However, substitution of wood with shells accelerated the ignition and flameout times of the boards. It increased the heat release without significantly affecting the percentage loss of the boards’ mass during exposure to fire.
Changes in the Characteristics of Pine Logging Residue during Storage in Forest Stands
2024, Wieruszewski, Marek, Kawalerczyk, Jakub, Stuper-Szablewska, Kinga, Walkiewicz, Joanna, Lieskovský, Martin, Jarzębski, Maciej, Mirski, Radosław
A significant amount of logging residue is produced during roundwood harvesting. Logs are often left in forest sites due to, for example, ecological or logistical aspects. Taking into account the fact that the number of studies focused on changes in the properties of the residue is very low, it was decided to conduct research on the effect of a three-year storage period in forest stands on the chemical properties and energy potential of the wood. The research design allowed for the determination of changes during up to three years of storage. The performed analysis showed a highly negative impact on the characteristics of the material. These adverse effects were probably caused by the activity of microorganisms such as fungi and bacteria, as evidenced by the increased concentrations of ergosterol and low-molecular-weight organic acids. Moreover, it was found that wood stored for three years was characterized by a lower cellulose content; an increased percentage of lignin; a reduced content of sterols (desmosterol, stigmasterol, lanosterol and β-sitosterol) and phenolic acids; and reduced antioxidant activity, as determined with the ABTS+ method. Storing logs also led to a reduction in the energy potential of the residues, as shown by a reduction in net and gross calorific value and an increased ash content.
Activated Carbon from Coconut Shells as a Modifier of Urea–Formaldehyde Resin in Particleboard Production
2024, Kawalerczyk, Jakub, Dukarska, Dorota, Antov, Petar, Stuper-Szablewska, Kinga, Dziurka, Dorota, Mirski, Radosław
Various methods for the effective modification of urea–formaldehyde (UF) adhesives, aimed at enhancing the performance of wood-based materials, have been continually explored worldwide. The aim of this work was to investigate and evaluate the effect of introducing small amounts (0.25–1.5%) of activated carbon from coconut shells (ACCS) in UF adhesive on the properties of particleboard. The performed investigations of the adhesive mixture’s properties showed an increase in both viscosity and reactivity. Moreover, the use of loadings of 0.75% and 1% had a positive effect on mechanical properties such as bending strength, modulus of elasticity, and internal bond. In these variants, a delay in the degradation of the adhesive bonds by water was also observed, as indicated by the lower thickness swelling values measured after 2 h. However, under long-term exposure to water, the modification had no considerable effect on the dimensional stability of the boards. Markedly, the addition of 1 and 1.5% of ACCS resulted in a reduction in formaldehyde content, which can be attributed to the excellent adsorption capacity of activated carbon. Overall, a loading of 1% was found to be optimal, resulting in improved strength, enhanced water resistance, and reduced formaldehyde content.
Properties of Lightweight Insulating Boards Produced from Triticale Straw Particles
2023, Lesiecki, Mariusz, Kawalerczyk, Jakub, Derkowski, Adam, Wieruszewski, Marek, Dziurka, Dorota, Mirski, Radosław
Insulating materials made from straw are becoming increasingly popular in the construction industry. Straw can be used in the construction of buildings as uncompressed straw chips or in the form of compressed panels. This study aimed to determine the possibility of manufacturing boards from straw particles with densities in the range of 150–400 kg/m3, allowing favorable mechanical properties while simultaneously providing high thermal and acoustic insulation properties. The study also analyzed the influence of the degree of carpentry density on the quality of the manufactured boards. The study shows that insulation boards can be produced from straw particles with satisfactory properties already at densities in the range of 200–150 kg/m3. Boards with this density have a compressive strength of 150 kPa, thermal resistance of 0.033–0.046 W/(m·K), and a sound absorption coefficient above 0.31.
Properties of fiber-gypsum composite formed on the basis of hemp (Cannabis sativa L.) fibers grown in Poland and natural gypsum
2023, Trociński, Adrian, Wieruszewski, Marek, Kawalerczyk, Jakub, Mirski, Radosław
: Properties of fiber-gypsum composite formed on the basis of hemp (Cannabis sativa L.) fibers grown in Poland and natural gypsum. The popularity of composites reinforced with natural fibers is constantly growing and therefore, they are a subject of many scientific works as well. An example of interesting concept is the use of hemp fibers to reinforce a gypsum matrix and therefore, presented study was aimed to determine the effect of their content on the properties of resultant composites. Moreover, the influence of setting temperature was also investigated. The scope of the research included determination of properties such as: density, setting time, bending strength, modulus of elasticity and thermal conductivity coefficient. Studies have shown that as the amount introduced fibers increases, the density of manufactured composites decreases. Furthermore, increase in the content of hemp causes a significant extension in setting time of the gypsum matrix. Based on the outcomes of mechanical properties, it was found that the optimal content of fibers is 4% and further increase in their share results in a deterioration of flexural strength characteristics. The increase in a setting temperature leads to thereduction in their bending strength and modulus of elasticity. Composites reinforced with hemp fibers demonstrate significantly improved thermal insulation properties
Coffee silverskin and cocoa pod husk modified with methacrylic acid as fillers for the urea-formaldehyde resin in plywood production
2025, Kawalerczyk, Jakub, Hoffmann, Maciej, Ekwińska, Maria, Stuper-Szablewska, Kinga, Woźniak, Magdalena, Mirski, Radosław
Selected Chemical and Physical Properties of Pine Wood Chips Inoculated with Aspergillus and Penicillium Mold Fungi
2023, Mirski, Radosław, Kawalerczyk, Jakub, Dziurka, Dorota, Stuper-Szablewska, Kinga, Walkiewicz, Joanna
Mold fungi representing genera of Penicillium and Aspergillus commonly develop on the surface of freshly harvested wood chips during storage. As a result, they are often considered as low-quality material and intended for incineration. Thus, the aim of the present study was to investigate the effect of wood chips infestation with mold fungi representing genera of Aspergillus and Penicillium on their basic chemical and physical properties, such as: chemical structure (evaluated with FTIR spectroscopy), mass loss and hygroscopicity, after an incubation of 3, 6 and 9 weeks. Based on the visual assessment and ergosterol content analysis, it was found that inoculation of wood chips with molds led to the intense fungal development on their surface. However, as observed in FTIR spectra, the presence of molds caused no changes in wood chemical structure. Furthermore, no mass loss and no significant increase in the hygroscopicity of wood were observed. Therefore, pine wood chips overgrown by studied genera of fungi seem to be a valuable material for various applications.
Effect of lysine-functionalized nanocellulose on urea-formaldehyde adhesive performance in particleboard production
2025, Kawalerczyk, Jakub, Dziurka, Dorota, Dukarska, Dorota, Mirski, Radosław
The effect of impregnation with fire retardant on the properties of particleboard bonded with PF/pMDI adhesive
2024, Kawalerczyk, Jakub, Dziurka, Dorota, Majlingová, Andrea, Lieskovský, Martin, Walkiewicz, Joanna, Mirski, Radosław
The tea leaves as a filler for uf resin plywood production
2023, Walkiewicz, Joanna, Kawalerczyk, Jakub, Mirski, Radosław, Szubert, Zuzanna
The addition of green tea leaves fractions < 0.315 mm as afiller to urea-formaldehyde resin to reduction of emission of formaldehyde from three-layer birch plywood was investigated. Moreover, other properties such as bonding quality and water resistance of plywood were investigated. It was found that green tea had an ability to absorb formaldehyde. This phenomenon was caused by phenolic compounds contained in green tea leaves. The addition of green tea in the amount of 20% and 25% resulted in a decrease in formaldehyde emission fromplywood comparing to the reference sample. Thebonding quality test showed that the addition of tea leaves as a filler did not affect thestrength properties of the tested bond lines.
The Effect of Treatment with Fire Retardant on Properties of Birch Veneer and Manufactured Fire-Resistant Plywood
2023, Kawalerczyk, Jakub, Dziurka, Dorota, Pinkowski, Grzegorz, Stachowiak-Wencek, Agata, Walkiewicz, Joanna, Mirski, Radosław
Nanocellulose functionalized with ethylenediamine as a modifier of urea-formaldehyde adhesive in particleboard production
2025, Kawalerczyk, Jakub, Dziurka, Dorota, Dukarska, Dorota, Mirski, Radosław
A comprehensive review of lignin-reinforced lignocellulosic composites: Enhancing fire resistance and reducing formaldehyde emission
2024, Iswanto, Apri Heri, Lee, Seng Hua, Hussin, Hazwan M., Hamidon, Tuan Sherwyn, Hajibeygi, Mohsen, Manurung, Harisyah, Solihat, Nissa Nurfajrin, Nurcahyani, Puji Rahmawati, Lubis, Muhammad Adly Rahandi, Antov, Petar, Savov, Viktor, Kristak, Lubos, Kawalerczyk, Jakub, Osvaldová, Linda Makovická, Farid, Samina, Selvasembian, Rangabhashiyam, Fatriasari, Widya
Comprehensive analysis of the chemical composition of conifer cones collected from Polish forests
2025, Kawalerczyk, Jakub, Stuper-Szablewska, Kinga, Woźniak, Magdalena, Brózdowski, Jakub, Przybylska-Balcerek, Anna, Wieruszewski, Marek, Mirski, Radosław
Experimental Analysis of Bonding in Steel Glued into Pine Timber
2024, Derkowski, Adam, Chuda-Kowalska, Monika, Kawalerczyk, Jakub, Dziurka, Dorota, Mirski, Radosław
Combining steel with wood has been practised for many years. The issue is related to two main areas, i.e., bonding steel elements with wood so that they serve as connectors facilitating the assembly of wood elements and bonding steel elements to wood beams to improve their load-bearing capacity. In the first case, the adhesives used may be relatively expensive and more difficult to apply, whereas in the second one, especially when steel elements are glued inside the glulam (GL) beams, it is better if the adhesives used are more accessible to apply and cheaper. As it seems rational to reinforce wood with high-modulus ties, research has been carried out to compare the connection quality of commercially available adhesives that can be used for this purpose. Moreover, thermosetting adhesives have been applied as an alternative and cheaper solution. Thermostat adhesives also have a high pH of the bond, which prevents the steel from rusting. The research shows that the load-bearing capacity of the bond depends on whether the bars are ribbed or sheet metal. Moreover, among thermosetting adhesives, the most favourable load-bearing values were obtained using a mixture of PF/pMDI (phenol formaldehyde resin/polymeric diphenylmethane diisocyanate) and powder from recycled tyres. The shear strength of these joints was 1.63 N/mm2 and 3.14 N/mm2 for flat specimens and specimens with ribbed bars, respectively.
Potential of Nanotechnology in Wood-Based Materials
2025, Kawalerczyk, Jakub, Dziurka, Dorota, Dukarska, Dorota, Walkiewicz, Joanna, Mirski, Radosław, Antonov, Petar, Lubis, Muhammad Adly Rahandi, Lee, Seng Hua, Taghiyari, Hamid R.
The effect of urea-formaldehyde adhesive modification with diisocyanate-functionalized nanocellulose on the properties of particleboard
2024, Kawalerczyk, Jakub, Dziurka, Dorota, Dukarska, Dorota, Woźniak, Magdalena, Walkiewicz, Joanna, Mirski, Radosław