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Ecological and Health Risk Assessments of Heavy Metals Contained in Sediments of Polish Dam Reservoirs
This study aimed at investigating the distribution of heavy metals (HMs: Zn, Pb, Cd, Ni, Cr, and Cu) in the bottom sediments of 28 reservoirs covered area of Poland. The paper evaluates the pollution of sediments with HMs and their potential toxic effects on aquatic organisms and human health on the basis of results provided by the Chief Inspectorate of Environmental Protection in Poland. The average concentrations of HMs in the bottom sediments of the reservoirs were as follows: Cd < Ni < Cr < Cu < Pb < Zn. (0.187, 7.30, 7.74, 10.62, 12.47, and 52.67 mg∙dm−3). The pollution load index values were from 0.05 to 2.45. They indicate contamination of the bottom sediments in seven reservoirs. The contamination-factor values suggest pollution with individual HMs in 19 reservoirs, primarily Cr, Ni, Cu, and Pb. The analysis showed that only two reservoirs had the potential for toxic effects on aquatic organisms due to high concentrations of Cd and Pb. The hazard index values for all the analyzed HMs were less than one. Therefore, there was no non-carcinogenic risk for dredging workers. The reservoirs were divided into two groups in terms of composition and concentration values. Reservoirs with higher concentrations of HMs in bottom sediments are dispersed, suggesting local pollution sources. For the second group of reservoirs, HMs’ concentrations may be determined by regional pollution sources. The analysis showed that Pb, Zn, and Cd concentrations are higher in older reservoirs and those with higher proportions of artificial areas in their catchments. Concentrations of Ni, Cu, and Cr are higher in reservoirs in south Poland and those with higher Schindler’s ratios.
Role of hydraulic parameters in the concentration and spatial distribution of heavy metals in sediments in a two-stage reservoir
Assessment of spatial distribution of sediment contamination with heavy metals in the two biggest rivers in Poland
Heavy Metals in River Sediments: Contamination, Toxicity, and Source Identification—A Case Study from Poland
This study investigated the spatial distribution, contamination, potential ecological risks and quantities of pollutant sources of six heavy metals (HMs) in sediments of 47 rivers. The catchments of the investigated rivers are situated in Poland, but some of them are located in Slovakia, the Czech Republic, and Germany. Cluster analysis was applied to analyze the spatial distribution of Cd, Cr, Cu, Ni, Pb, and Zn in river sediments. Moran I and Getis-Ord Gi* statistics were calculated to reveal the distribution pattern and hotspot values. Principal component analysis (PCA) and positive matrix factorization (PMF) were used to identify pollution sources. Furthermore, geochemical indices and sediment quality guidelines allowed us to assess sediment contamination and potential toxic effects on aquatic biota. The results showed that in 1/3rd of the rivers, the HM pattern and concentrations indicate sediment contamination. The EF, PLI, and MPI indices indicate that concentrations were at a rather low level in 2/3rd of the analyzed rivers. Only in individual rivers may the HMs have toxic effects on aquatic biota. Spatial autocorrelation analysis using the Moran I statistic revealed a random and dispersed pattern of HMs in river sediments. PCA analysis identified two sources of HMs’ delivery to the aquatic environment. Cr, Cu, Ni, Pb, and Zn originate from point and non-point sources, while Cd concentrations have a dominant natural origin. The PMF identified three sources of pollution. Among them, urban pollution sources are responsible for Cu delivery, agricultural pollution for Zn, and industrial pollution for Ni and Cr. Moreover, the analysis showed no relationship between catchment land-use patterns and HM content in river sediments.