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Modified Buckwheat Husk as a Filler for Urea–Formaldehyde Resin in Plywood Production
The aim of the presented research was to determine the suitability of both non-modified and modified buckwheat husk (BH) as a filler for urea–formaldehyde adhesive in plywood production. The effect of two modification methods, acetylation and silanization, was investigated. Infrared spectroscopy outcomes confirmed that both acetylation and silanization of the filler had occurred. Based on the results, it was found that the introduction of BH had a significant effect on both the adhesive properties and the characteristics of the manufactured plywood. The application of non-modified husks led to a reduction in viscosity and an extension of the gelation time, and the produced plywood boards were characterized by reduced bonding quality and increased delamination. Modification of the husk surface by acetylation and silanization with 3-aminopropyltriethoxysilane contributed to the noticeable improvement in the resin properties. On the other hand, the improvement in plywood properties, consisting of the increase in bonding quality and reduced delamination, was observed only in the case of the silanized husk. Furthermore, the use of non-modified and acetylated husk did not significantly influence the formaldehyde emission. The reduction in the investigated emission of formaldehyde was observed only in the case of variants containing 15 and 20% of silanized buckwheat husk.
Morphological Features of PUR-Wood Particle Composite Foams
The aim of this study was to apply waste wood particles (WP) with different sizes from primary wood processing as a filler for open-cell PUR foams. For this purpose, various wood particle sizes were added as a filler for polyurethane foams (PUR). The effects of the addition of of 0.05–<0.125 mm, 0.125–<0.315 mm, 0.315–1.25 mm, and >1.25–2.0 of WP to the polyurethane matrix on the density, the kinetics of PUR foaming, the cell structure, and the morphology were investigated. Scanning electron microscope (SEM) and X-ray computer tomography were used. Based on the results, it was found that the addition of WP in the amount of 10% leads to an increase in density with an increase in particle size. The research shows that the morphology of the PUR-WP foam is influenced by its particle size. The difference in the number and size of cells in PUR-WP composites depends on the wood particle size. The addition of dust causes the formation of cells of much smaller sizes; confirmed by SEM images. Moreover, computer tomography clearly demonstrates that the WP are well-dispersed within the foams’ structures.
The effect of the tree dieback process on the mechanical properties of pine (Pinus sylvestris L.) wood
As a result of the progressing climate changes, there is an increase in the volume of pine deadwood harvested each year from Polish forests. Its presence is an important part of the forest ecosystem; however, there are some indications that the material obtained from dying trees can be characterized by lower quality and properties. Taking into account the growing issue of tree dieback, the volume of pine wood annually harvested in Poland, and the importance of wooden products from an economic standpoint, preliminary research aimed at recognizing the process and its effect on the mechanical properties was conducted. Model trees in Brzeg Forest District were selected based on the crown defoliation. The properties of wood obtained from trees representing three different categories of soundness were determined according to the relevant standards. Based on the results of density, modulus of elasticity, bending strength, and compressive strength, it was found that there were statistically significant differences in wood quality depending on the condition of the tree. The results were particularly interesting in the case of compressing strength, where a healthy tree of lower density showed a similar strength to a dying tree with a much higher density.
Selected Chemical and Physical Properties of Pine Wood Chips Inoculated with Aspergillus and Penicillium Mold Fungi
Mold fungi representing genera of Penicillium and Aspergillus commonly develop on the surface of freshly harvested wood chips during storage. As a result, they are often considered as low-quality material and intended for incineration. Thus, the aim of the present study was to investigate the effect of wood chips infestation with mold fungi representing genera of Aspergillus and Penicillium on their basic chemical and physical properties, such as: chemical structure (evaluated with FTIR spectroscopy), mass loss and hygroscopicity, after an incubation of 3, 6 and 9 weeks. Based on the visual assessment and ergosterol content analysis, it was found that inoculation of wood chips with molds led to the intense fungal development on their surface. However, as observed in FTIR spectra, the presence of molds caused no changes in wood chemical structure. Furthermore, no mass loss and no significant increase in the hygroscopicity of wood were observed. Therefore, pine wood chips overgrown by studied genera of fungi seem to be a valuable material for various applications.
The effect of urea-formaldehyde adhesive modification with propylamine on the properties of manufactured plywood
The effect of impregnation with fire retardant on the properties of particleboard bonded with PF/pMDI adhesive
APTES-Modified Nanocellulose as the Formaldehyde Scavenger for UF Adhesive-Bonded Particleboard and Strawboard
This work examines the possibility of applying non-modified nanocellulose and nanocellulose functionalized with 3-aminopropyltriethoxysilane (APTES) as a formaldehyde scavenger for commonly used urea-formaldehyde (UF) adhesive. The effect of silanization was determined with the use of Fourier transform infrared spectroscopy (FTIR), flame atomic absorption spectrometry (FAAS), and elemental analysis. Moreover, the ability of cellulosic nanoparticles to absorb the formaldehyde from an aqueous solution was investigated. After homogenization, cured UF adhesives were examined with the use of FTIR, energy-dispersive spectroscopy (SEM-EDS), and the perforator method to determine the content of formaldehyde. Manufactured boards made of rape straw particles and wood particles were tested in terms of their physico-mechanical properties and formaldehyde emission. Studies have shown that the applied method of silanization was effective. Furthermore, in the case of non-modified nanocellulose, no sign of formaldehyde scavenging ability was found. However, the functionalization of cellulosic nanoparticles with APTES containing an amino group led to the significant reduction of formaldehyde content in both the aqueous solution and the UF adhesive. The mechanical properties of both strawboards and particleboards were improved due to the nanocellulose reinforcement; however, no effect of silanization was found. Nevertheless, functionalization with APTES contributed to a decrease in formaldehyde emission from boards, which was not found in the case of the introduction of non-modified cellulosic nanoparticles.
The effect of urea-formaldehyde adhesive modification with diisocyanate-functionalized nanocellulose on the properties of particleboard
The Possibility of Using Pine Bark Particles in the Chipboard Manufacturing Process
This research evaluated the possibility of using sawmill by-products from the roundwood-processing line in the production of wood-based panels. Due to its number of favorable properties, interesting chemical composition and large reserves resulting from the lack of industrial applications, the research focused particularly on the use of bark. Manufactured variants of boards differed in the proportions of wood chips to bark (70:30, 60:40, 50:50). Moreover, the boards containing only wood chips and a mixture of chips and sawdust were used as references. Urea-formaldehyde adhesive mixed with ammonium nitrate as a hardener was applied as a binding agent for the boards. Based on the mechanical properties (modulus of elasticity, modulus of rupture, internal bonding), physical properties (density, thickness swelling, water absorption) and content and emission of formaldehyde, it was found that it is possible to produce boards characterized by good properties from sawmill by-products without advanced processing. Moreover, the use of bark instead of sawdust in order to increase the homogeneity of the cross-section allows one to obtain panels with significantly lower formaldehyde emission and water uptake.
The Application of Various Bark Species as a Fillers for UF Resin in Plywood Manufacturing
The aim of the presented study was to apply various bark species (birch, beech, maple, pine and spruce) as fillers for urea-formaldehyde (UF) resin in three-layer plywood manufacturing. For this purpose, all types of bark were ground and added to the adhesive mixture. The resultant plywood was subjected to investigations of the following: tensile strength, modulus of elasticity (MOE), bending strength (MOR) and formaldehyde emission. The results indicate a reduction in the tensile strength. Moreover, the lack of significant improvement in strength parameters can be explained by too high a load of the filler (20 wt%). In the case of formaldehyde emissions, a reduction was observed for birch (B-1), beech (B-2), maple (B-3) and pine bark (B-4). In addition, an increase in the emission of formaldehyde was recorded only for spruce bark.
Properties of Particle Boards Containing Polymer Waste
Nowadays, a significant increase in interest in renewable energy sources can be observed. Wind farms have been one of the solutions representing this trend for many years. One of the important elements of windmills is the blades. The data indicate that what to do with the blades after their use is a global problem, and so it is important to find a way to recycle them. Hence, this work aimed to use these blades in the production of wood-based materials. Two fractions of a fragmented blade were used for the tests: a small one and large one. Boards characterized by densities of 650 kg/m3 and 700 kg/m3 were produced, in which the assumed substitution of the wood material with a polymer was 20% or 40%. Mechanical properties such as bending strength (MOR), modulus of elasticity (MOE), and internal bond strength (IB) were investigated. The 2S65 variant achieved the highest static bending strength and a modulus of elasticity of 2625 N/mm2. The second best result was noted for the 4S65 variant, which was significantly different from the 2S65 variant. In the case of the variants with a density of 700 kg/m3, no significant differences were found and their results were significantly lower. Moreover, research on thickness swelling (TS) after 24 h of immersion and water absorption (WA) were also conducted. The obtained results indicate that the manufactured boards are characterized by good physical and mechanical properties.
Wood Particles of Various Sizes from Primary Wood Processing as Filler in Rigid Polyurethane Foams
The Effect of Treatment with Fire Retardant on Properties of Birch Veneer and Manufactured Fire-Resistant Plywood
The Possibility to Use Pine Timber Pieces with Small Size in the Production of Glulam Beams
Engineered wood products, such as glulam beams, attract much attention from the building industry in recent years. Therefore, there is a constant necessity to seek new models of structural beams, which assume the use of outsized sawn wood pieces as an alternative for the standard construction timber. Three variants of glulam beams, composed of the main yield and side boards arranged in various structures, were proposed. Moreover, the usefulness of wedge-jointed, small-sized timber pieces was also investigated. The manufactured beams were tested, in terms of their mechanical properties, such as bending strength, elastic energy, modulus of elasticity, and resilience. The outcomes have shown that the beams manufactured using wedge-bonded timber of lower grade do not deviate considerably from beams produced from homogeneous lamellas. Furthermore, the results of modulus of elasticity, in the case of the three-layered beams composed of both small-sized non-homogenous main yield and side boards, exceeded the requirements from EN 14080. It allowed us to classify the obtained materials as GL 32c, which is the highest grade specified within the standard.
The effect of storage conditions on the strength characteristic of glulam beams
Despite many outdoors applications, the number of works aimed to determine the effect of changing conditions on the properties of glulam beams, in particular those produced in non-standard arrangements, is few. Therefore, the aim of this study was to assess changes in flexural strength properties (MOE, MOR) of the beams stored for 30 months in varying conditions. Analyzed variants of pine GLT beams included five-meter-long structural elements reinforced with oak timber, high-quality pine timber and steel rods stored both in the roofed shed outdoors and inside the climatic chamber. Moisture content of the beam varied significantly depending on the placement of the sensors (on the surface or inside the beam). The average modulus of elasticity after 30 months of storage decreased by approx. 7% compared to initial values. The results varied depending on both the assumed beam arrangement and the applied conditions.
Properties of Rigid Polyurethane Foam Filled with Sawdust from Primary Wood Processing
In this study, the possibility of using sawdust, a by-product of primary wood processing, as a filler (WF) for rigid polyurethane (PUR) foams was investigated. The effects of the addition of 5, 10, 15 and 20% of WF particles to the polyurethane matrix on the foaming process, cell structure and selected physical-mechanical properties such as density, thermal conductivity, dimensional stability, water absorption, brittleness, compressive and bending strengths were evaluated. Based on the results, it was found that the addition of WF in the amount of up to 10% does not significantly affect the kinetics of the foam foaming process, allowing the reduction of their thermal conductivity, significantly reducing brittleness and maintaining high dimensional stability. On the other hand, such an amount of WF causes a slight decrease in the compressive strength of the foam, a decrease in its bending strength and an increase in water absorption. However, it is important that in spite of the observed decrease in the values of these parameters, the obtained results are satisfactory and consistent with the parameters of insulation materials based on rigid PUR foam, currently available on the market.
