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How thermal treatment affects the chemical composition and the physical, mechanical and swelling properties of Scots pine juvenile and mature wood
AbstractHigh variations in juvenile wood properties in the radial direction and its worse performance than mature wood make it less suitable for some applications and often treated as waste material. This study aimed to assess how thermal modification affects the chemical composition and the physical, mechanical and swelling properties of Scots pine juvenile and mature wood. An additional goal was to evaluate if the modification can equalise the differences in selected properties of juvenile wood to those of mature wood so that from waste material, juvenile wood can become a fully-fledged raw material for various industrial applications. Thermal treatment at 220 °C influenced wood chemical composition, degrading mainly hemicelluloses but also affecting cellulose and lignin, which resulted in a reduction of hydroxyls and carbonyl/carboxyl groups. These changes were more pronounced for mature than juvenile wood. It reduced mass loss and swelling rate, and increased swelling pressure in the tangential and radial directions to a higher degree for juvenile than mature wood. Changes in mechanical properties in compression were statistically significant only for mature wood, while wood hardness remained unaffected. Although the applied heat treatment improved the performance of juvenile wood by reducing its swelling rate, it did not equalise the examined properties between juvenile and mature wood. Since higher juvenile wood proportion is expected in the wood supply from the future intensively managed forests, there is still a need to find suitable modification methods or better processing techniques so that instead of being thrown away as waste, it could be used broadly in various industrial applications.
Swelling Behaviour of Bamboo (Phyllostachys pubescens)
Bamboo is a plant with various applications. As a natural, renewable material that exhibits good mechanical performance, it seems to be an interesting alternative to wood, which has become a scarce and expensive commodity. However, comprehensive knowledge of its properties is necessary to maximise its potential for various industrial purposes. The swelling behaviour of bamboo is one of the features that has not yet been sufficiently investigated. Therefore, in this research, we aimed to measure and analyse the swelling pressure and kinetics of bamboo blocks. The results show that similar to wood, the swelling kinetics of bamboo depend on its density: the denser the tissue, the higher the maximum swelling value recorded. The maximum tangential swelling measured was about 5%–6%, which is lower than the value for the most commonly used wood species. Swelling pressure ranged from 1.16 MPa to 1.39 MPa, depending on the bamboo density: the denser the sample, the shorter the time required to reach maximum swelling pressure. Like in wood, the smallest linear increase in size due to swelling was observed in the longitudinal direction (0.71%). However, opposite to wood, more pronounced swelling was recorded in the radial direction (over 7%) than in the tangential direction (nearly 6%). The results show that bamboo’s swelling behaviour makes it a good material for use in variable humidity conditions, being more favourable than the unmodified wood of many species.