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Activated Carbon from Coconut Shells as a Modifier of Urea–Formaldehyde Resin in Particleboard Production
Various methods for the effective modification of urea–formaldehyde (UF) adhesives, aimed at enhancing the performance of wood-based materials, have been continually explored worldwide. The aim of this work was to investigate and evaluate the effect of introducing small amounts (0.25–1.5%) of activated carbon from coconut shells (ACCS) in UF adhesive on the properties of particleboard. The performed investigations of the adhesive mixture’s properties showed an increase in both viscosity and reactivity. Moreover, the use of loadings of 0.75% and 1% had a positive effect on mechanical properties such as bending strength, modulus of elasticity, and internal bond. In these variants, a delay in the degradation of the adhesive bonds by water was also observed, as indicated by the lower thickness swelling values measured after 2 h. However, under long-term exposure to water, the modification had no considerable effect on the dimensional stability of the boards. Markedly, the addition of 1 and 1.5% of ACCS resulted in a reduction in formaldehyde content, which can be attributed to the excellent adsorption capacity of activated carbon. Overall, a loading of 1% was found to be optimal, resulting in improved strength, enhanced water resistance, and reduced formaldehyde content.
Current Trends in the Use of Biomass in the Manufacture of Rigid Polyurethane Foams: A Review
This paper discusses methods of using biomass from the agriculture, forestry, food and aquaculture industries as potential raw materials for bio-polyols and as fillers in the production of rigid polyurethane (RPUR) foams. Various aspects of obtaining bio-polyols are discussed, as well as the impact of replacing petrochemical polyols with bio-polyols on the properties of foams. Special attention is paid to the conversion of vegetable oils and lignin. Another important aspect of the research is the use of biomass as foam fillers. Chemical and physical modifications are discussed, and important factors, such as the type and origin of biomass, particle size and amount, affecting the foaming process, microstructure and properties of RPUR foams are identified. The advantages and disadvantages of using biomass in foam production are described. It is found that bio-polyols can replace (at least partially) petrochemical polyols while maintaining the high insulation and strength of foams. In the case of the use of biomass as fillers, it is found that the shaping of their properties is largely dependent on the specific characteristics of the filler particles. This requires further research into process optimization but allows for the fine-tuning of RPUR foam properties to meet specific requirements.
Modified Buckwheat Husk as a Filler for Urea–Formaldehyde Resin in Plywood Production
The aim of the presented research was to determine the suitability of both non-modified and modified buckwheat husk (BH) as a filler for urea–formaldehyde adhesive in plywood production. The effect of two modification methods, acetylation and silanization, was investigated. Infrared spectroscopy outcomes confirmed that both acetylation and silanization of the filler had occurred. Based on the results, it was found that the introduction of BH had a significant effect on both the adhesive properties and the characteristics of the manufactured plywood. The application of non-modified husks led to a reduction in viscosity and an extension of the gelation time, and the produced plywood boards were characterized by reduced bonding quality and increased delamination. Modification of the husk surface by acetylation and silanization with 3-aminopropyltriethoxysilane contributed to the noticeable improvement in the resin properties. On the other hand, the improvement in plywood properties, consisting of the increase in bonding quality and reduced delamination, was observed only in the case of the silanized husk. Furthermore, the use of non-modified and acetylated husk did not significantly influence the formaldehyde emission. The reduction in the investigated emission of formaldehyde was observed only in the case of variants containing 15 and 20% of silanized buckwheat husk.
The effect of urea-formaldehyde adhesive modification with diisocyanate-functionalized nanocellulose on the properties of particleboard
Properties of sandwich boards with a core made of bio-composite particleboard containing wood particles and walnut shells
AbstractThe aim of the research was to investigate the possibility of producing bio-composite particleboard with a density reduced to 500–550 kg/m3, containing 25% and 50% of walnut shells. In addition, the study also concerned the possibility of using these materials in sandwich systems. Based on the results, it was found that partial replacement of wood particles with ground shells leads to a significant reduction in the strength of the boards bonded with urea-formaldehyde (UF) resin. However, the implementation of a hybrid gluing method consisting of gluing wood particles with UF resin and walnut shells with 4,4′-methylenediphenyl isocyanate (pMDI) caused a significant improvement in the strength of the boards, especially for the variant with the highest shells content. Despite that, the manufactured materials still do not meet the requirements for furniture boards. The next step of the research has shown that these boards can perform well as a core layer in the sandwich boards covered with high-strength HDF boards. Moreover, it was found that increasing the share of walnut shells positively affected the dimensional stability of the resultant boards (thickness swelling and water absorption). However, substitution of wood with shells accelerated the ignition and flameout times of the boards. It increased the heat release without significantly affecting the percentage loss of the boards’ mass during exposure to fire.
The effect of wood particles polyesterification with sorbitol and citric acid on the properties of particleboard produced with the use of PF/pMDI adhesive
AbstractThis study investigated the effect of pine particle polyesterification with the mixture of sorbitol and citric acid (SCA) on the properties of particleboard bonded with the PF/pMDI hybrid resin. The use of SCA with a concentration of 35% contributed to improvement in the internal bond of the particleboards, their water resistance and dimensional stability. However, lowering the concentration to 25% resulted in a deterioration of the properties of produced materials. The effect of different loadings of pMDI in the PF/pMDI resin (0%, 5%, 15%, 25%) was also investigated and the outcomes showed a positive effect of the share of 15% and 25%. Furthermore, boards made of treated particles were characterized by slightly better flammable properties (lower mass loss, flashing point temperature and delayed ignition), and the visibility of the effect increased with the increase in the concentration of the impregnate. The results also indicate that the introduction of pMDI may also influence the ignition of the board.