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Effect of lysine-functionalized nanocellulose on urea-formaldehyde adhesive performance in particleboard production
Properties of the water-resistant plywood glued with PF resin with the addition of tannin filler and nanoclay
Modified Buckwheat Husk as a Filler for Urea–Formaldehyde Resin in Plywood Production
The aim of the presented research was to determine the suitability of both non-modified and modified buckwheat husk (BH) as a filler for urea–formaldehyde adhesive in plywood production. The effect of two modification methods, acetylation and silanization, was investigated. Infrared spectroscopy outcomes confirmed that both acetylation and silanization of the filler had occurred. Based on the results, it was found that the introduction of BH had a significant effect on both the adhesive properties and the characteristics of the manufactured plywood. The application of non-modified husks led to a reduction in viscosity and an extension of the gelation time, and the produced plywood boards were characterized by reduced bonding quality and increased delamination. Modification of the husk surface by acetylation and silanization with 3-aminopropyltriethoxysilane contributed to the noticeable improvement in the resin properties. On the other hand, the improvement in plywood properties, consisting of the increase in bonding quality and reduced delamination, was observed only in the case of the silanized husk. Furthermore, the use of non-modified and acetylated husk did not significantly influence the formaldehyde emission. The reduction in the investigated emission of formaldehyde was observed only in the case of variants containing 15 and 20% of silanized buckwheat husk.
Nanocellulose functionalized with ethylenediamine as a modifier of urea-formaldehyde adhesive in particleboard production
The effect of veneer-surface modification with fumed nanosilica on the selected properties of water-resistant plywood
Properties of sandwich boards with a core made of bio-composite particleboard containing wood particles and walnut shells
AbstractThe aim of the research was to investigate the possibility of producing bio-composite particleboard with a density reduced to 500–550 kg/m3, containing 25% and 50% of walnut shells. In addition, the study also concerned the possibility of using these materials in sandwich systems. Based on the results, it was found that partial replacement of wood particles with ground shells leads to a significant reduction in the strength of the boards bonded with urea-formaldehyde (UF) resin. However, the implementation of a hybrid gluing method consisting of gluing wood particles with UF resin and walnut shells with 4,4′-methylenediphenyl isocyanate (pMDI) caused a significant improvement in the strength of the boards, especially for the variant with the highest shells content. Despite that, the manufactured materials still do not meet the requirements for furniture boards. The next step of the research has shown that these boards can perform well as a core layer in the sandwich boards covered with high-strength HDF boards. Moreover, it was found that increasing the share of walnut shells positively affected the dimensional stability of the resultant boards (thickness swelling and water absorption). However, substitution of wood with shells accelerated the ignition and flameout times of the boards. It increased the heat release without significantly affecting the percentage loss of the boards’ mass during exposure to fire.
Optimization of Isocyanate Content in PF/pMDI Adhesive for the Production of High-Performing Particleboards
Due to the fact that impregnation with fire retardant usually reduces the strength of the produced particleboards, this research was carried out to investigate whether it is possible to use phenol–formaldehyde (PF) resin modified using various amounts (0%, 5%, 10%, 15%, and 20%) of polymeric 4,4′-methylene diphenyl diisocyanate (pMDI) for this purpose. The need to optimize the addition of pMDI is particularly important due to health and environmental aspects and high price. Furthermore, the curing process of hybrid resins is still not fully explained, especially in the case of small loadings. Manufactured particleboards differed in the share of impregnated particles (50% and 100%). The mixture of potassium carbonate and urea was used as the impregnating solution. Based on the outcomes of hybrid resins properties, it was found that the addition of pMDI leads to the increase in solid content, pH, and viscosity of the mixtures, to the improvement in resin reactivity determined using differential scanning calorimetry and to the decrease in thermal stability in the cured state evaluated using thermogravimetric analysis. Moreover, particleboard property results have shown that using impregnated particles (both 50% and 100%) decreased the strength of manufactured boards bonded using neat PF resin. However, the introduction of pMDI allowed us to compensate for the negative impact of fire-retardant-treated wood and it was found that the optimal loading of pMDI for the board containing 50% of impregnated particles is 5% and for board made entirely of treated wood it is 10%.
Current Trends in the Use of Biomass in the Manufacture of Rigid Polyurethane Foams: A Review
This paper discusses methods of using biomass from the agriculture, forestry, food and aquaculture industries as potential raw materials for bio-polyols and as fillers in the production of rigid polyurethane (RPUR) foams. Various aspects of obtaining bio-polyols are discussed, as well as the impact of replacing petrochemical polyols with bio-polyols on the properties of foams. Special attention is paid to the conversion of vegetable oils and lignin. Another important aspect of the research is the use of biomass as foam fillers. Chemical and physical modifications are discussed, and important factors, such as the type and origin of biomass, particle size and amount, affecting the foaming process, microstructure and properties of RPUR foams are identified. The advantages and disadvantages of using biomass in foam production are described. It is found that bio-polyols can replace (at least partially) petrochemical polyols while maintaining the high insulation and strength of foams. In the case of the use of biomass as fillers, it is found that the shaping of their properties is largely dependent on the specific characteristics of the filler particles. This requires further research into process optimization but allows for the fine-tuning of RPUR foam properties to meet specific requirements.
Morphological Features of PUR-Wood Particle Composite Foams
The aim of this study was to apply waste wood particles (WP) with different sizes from primary wood processing as a filler for open-cell PUR foams. For this purpose, various wood particle sizes were added as a filler for polyurethane foams (PUR). The effects of the addition of of 0.05–<0.125 mm, 0.125–<0.315 mm, 0.315–1.25 mm, and >1.25–2.0 of WP to the polyurethane matrix on the density, the kinetics of PUR foaming, the cell structure, and the morphology were investigated. Scanning electron microscope (SEM) and X-ray computer tomography were used. Based on the results, it was found that the addition of WP in the amount of 10% leads to an increase in density with an increase in particle size. The research shows that the morphology of the PUR-WP foam is influenced by its particle size. The difference in the number and size of cells in PUR-WP composites depends on the wood particle size. The addition of dust causes the formation of cells of much smaller sizes; confirmed by SEM images. Moreover, computer tomography clearly demonstrates that the WP are well-dispersed within the foams’ structures.
The effect of a phenol-formaldehyde adhesive reinforcement with nanocellulose on the pressing parameters of plywood
Researchon improving the reactivity of phenol-formaldehyde (PF) resin and thepossibility of lowering the pressing parameters of wood-based materials manufactured with its participation are still progressing. Due to a number of favorable properties, nanocellulose(NCC) is gaining more and more popularity as a modifier ofwood adhesives. Therefore, theobjective of the study was to assess the possible reduction of plywood pressing parameters due to the reinforcement of PF resin with NCC. Based on the bonding quality results it was found that there is a possibility to reduce pressing time by 25% and pressing temperature by 7%. Moreover, the outcomes of mechanical properties (modulus of elasticity and bending strength) of manufactured plywood indicate that theoretically it could be possible to decrease the pressing parameters even more. However, the shear strength of the glue joints was considered to be alimiting factor for further reduction. The results of delamination test show that plywood bonded with phenolic resin have no tendency to delaminate. Thus, it can be concluded that NCC can be used as a modifier for PF resin which can contribute to the reduction of pressing time and pressing temperature during the plywood manufacturing process.
The effect of urea-formaldehyde adhesive modification with diisocyanate-functionalized nanocellulose on the properties of particleboard
Modification of Urea-Formaldehyde Resin with Triethylenetetramine: Effect on Adhesive Properties and Plywood Strength
Due to its multiple amino groups, triethylenetetramine (TETA) can be used as an effective formaldehyde scavenger contributing to the reduction in formaldehyde emission from plywood. This study aimed to evaluate the effect of small TETA loadings on the properties of urea-formaldehyde (UF) resin and the performance of the resulting plywood. Adhesive mixtures containing 0%, 0.5%, 1.0%, and 1.5% TETA were prepared and characterized in terms of pH, viscosity, solids content, and gel time. The incorporation of TETA significantly increased adhesive pH and gel time, while viscosity and solid content were not significantly affected. The analysis of formaldehyde content and spectroscopic and thermogravimetric analyses of the cured adhesives showed reduced formaldehyde content, changes in chemical structure, and enhanced thermal stability at lower temperatures but accelerated degradation at higher temperatures. Formaldehyde emission from plywood was reduced; however, bonding quality and mechanical performance decreased with higher TETA content. Nevertheless, the wet shear strength of all variants exceeded 1 N/mm2. Adhesive formulation containing 0.5% TETA was selected as the optimal variant, providing environmental benefits while maintaining satisfactory plywood performance.
Properties of Rigid Polyurethane Foam Filled with Sawdust from Primary Wood Processing
In this study, the possibility of using sawdust, a by-product of primary wood processing, as a filler (WF) for rigid polyurethane (PUR) foams was investigated. The effects of the addition of 5, 10, 15 and 20% of WF particles to the polyurethane matrix on the foaming process, cell structure and selected physical-mechanical properties such as density, thermal conductivity, dimensional stability, water absorption, brittleness, compressive and bending strengths were evaluated. Based on the results, it was found that the addition of WF in the amount of up to 10% does not significantly affect the kinetics of the foam foaming process, allowing the reduction of their thermal conductivity, significantly reducing brittleness and maintaining high dimensional stability. On the other hand, such an amount of WF causes a slight decrease in the compressive strength of the foam, a decrease in its bending strength and an increase in water absorption. However, it is important that in spite of the observed decrease in the values of these parameters, the obtained results are satisfactory and consistent with the parameters of insulation materials based on rigid PUR foam, currently available on the market.
The effect of wood particles polyesterification with sorbitol and citric acid on the properties of particleboard produced with the use of PF/pMDI adhesive
AbstractThis study investigated the effect of pine particle polyesterification with the mixture of sorbitol and citric acid (SCA) on the properties of particleboard bonded with the PF/pMDI hybrid resin. The use of SCA with a concentration of 35% contributed to improvement in the internal bond of the particleboards, their water resistance and dimensional stability. However, lowering the concentration to 25% resulted in a deterioration of the properties of produced materials. The effect of different loadings of pMDI in the PF/pMDI resin (0%, 5%, 15%, 25%) was also investigated and the outcomes showed a positive effect of the share of 15% and 25%. Furthermore, boards made of treated particles were characterized by slightly better flammable properties (lower mass loss, flashing point temperature and delayed ignition), and the visibility of the effect increased with the increase in the concentration of the impregnate. The results also indicate that the introduction of pMDI may also influence the ignition of the board.
Characterisation of Wood Particles Used in the Particleboard Production as a Function of Their Moisture Content
The properties of particleboards and the course of their manufacturing process depend on the characteristics of wood particles, their degree of fineness, geometry, and moisture content. This research work aims to investigate the physical properties of wood particles used in the particleboard production in dependence on their moisture content. Two types of particles currently used in the production of three-layer particleboards, i.e., microparticles (MP) for the outer layers of particleboards and particles for the core layers (PCL), were used in the study. The particles with a moisture content of 0.55%, 3.5%, 7%, 10%, 15%, and 20% were tested for their poured bulk density (ρp), tapped bulk density (ρt), compression ratio (k), angle of repose (αR), and slippery angle of repose (αs). It was found that irrespective of the fineness of the particles, an increase in their moisture content caused an increase in the angle of repose and slippery angle of repose and an increase in poured and tapped bulk density, while for PCL, the biggest changes in bulk density occurred in the range up to 15% of moisture content, and for MP in the range above 7% of moisture content, respectively. An increase in the moisture content of PCL in the range studied results in a significant increase in the compression ratio from 47.1% to 66.7%. The compression ratio of MP increases only up to 15% of their moisture content—a change of value from 47.1% to 58.7%.
Alternative Wood Raw Material Sources in Particleboard and OSB Production—Challenges and Perspectives
This review examines the potential use of alternative wood raw materials, including fast-growing plantation species, juvenile wood, non-plantation species, and recycled wood, in the production of particleboard (PB) and oriented strand board (OSB). In light of the ongoing challenges faced by the wood-based industry in securing a stable and sustainable supply of raw materials, these alternatives present several advantages, such as cost-effectiveness, greater availability, and reduced reliance on natural forest resources. Fast-growing plantation species and juvenile wood are particularly suited for lightweight applications, while non-plantation species and recycled wood contribute to sustainability goals by lowering environmental impact and promoting resource efficiency. Nonetheless, the successful integration of these materials requires overcoming certain challenges, including variability in their physical and mechanical properties, as well as the need for tailored adhesive systems and processing parameters. This review examines strategies to optimize production processes and enhance the utilization of waste materials while emphasizing the role of alternative raw materials in advancing circular economy principles. The findings highlight the importance of future research to improve material knowledge, technological solutions, and industry practices, thereby supporting the sustainable development of the wood-based materials sector.
Properties of Particle Boards Containing Polymer Waste
Nowadays, a significant increase in interest in renewable energy sources can be observed. Wind farms have been one of the solutions representing this trend for many years. One of the important elements of windmills is the blades. The data indicate that what to do with the blades after their use is a global problem, and so it is important to find a way to recycle them. Hence, this work aimed to use these blades in the production of wood-based materials. Two fractions of a fragmented blade were used for the tests: a small one and large one. Boards characterized by densities of 650 kg/m3 and 700 kg/m3 were produced, in which the assumed substitution of the wood material with a polymer was 20% or 40%. Mechanical properties such as bending strength (MOR), modulus of elasticity (MOE), and internal bond strength (IB) were investigated. The 2S65 variant achieved the highest static bending strength and a modulus of elasticity of 2625 N/mm2. The second best result was noted for the 4S65 variant, which was significantly different from the 2S65 variant. In the case of the variants with a density of 700 kg/m3, no significant differences were found and their results were significantly lower. Moreover, research on thickness swelling (TS) after 24 h of immersion and water absorption (WA) were also conducted. The obtained results indicate that the manufactured boards are characterized by good physical and mechanical properties.
Utilization of Pine and Birch Juvenile Wood for Low-Density Particleboard Production
This study investigated the effect of using juvenile pine and birch wood for the production of particleboards with lowered density, glued with urea-formaldehyde (UF) resin. The wood used was characterized by a number of annual rings ranging from 5 to 13, which ensured that only juvenile wood was used in the study. In addition to the basic characteristics of the wood particles obtained from this type of raw material, the density profiles of the manufactured particleboards, the internal bond, bending strength, modulus of elasticity, swelling, and water absorption after short-term water exposure (2 h) were also investigated. The results were compared to particleboards made from industrial wood particles from mature wood. It was found that particleboards made from juvenile pine wood exhibited higher internal bond than those made from juvenile birch wood. The bending strength of boards made from both types of juvenile wood was comparable to that of industrial particleboards; however, the modulus of elasticity of the particleboards made from juvenile pine was lower, which indicates reduced stiffness. These particleboards also showed higher swelling and water absorption, which may limit their durability under humid conditions. In contrast, birch boards exhibited lower internal bond, but their bending strength and modulus of elasticity were similar to those of industrial particles-based particleboards. Birch boards also showed slightly better water resistance than pine particleboards made from juvenile wood. However, their swelling remained higher than that of industrial particleboards. Overall, particleboards made from juvenile wood, especially birch, show good potential for further research.
