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Determination of Polycyclic Aromatic Hydrocarbons (PAHS) in Sewage Sludge and Compost by Dispersive Solid-Phase Microextraction (SPME) and Ultra-High Performance Liquid Chromatography (UHPLC) with Diode Array Detection (DAD)
Nanoparticles for Sustainable Agriculture: Assessment of Benefits and Risks
Nanotechnology is rapidly emerging as a transformative force in agriculture, offering innovative solutions to support sustainable crop production. This review examines the interactions between nanoparticles (NPs) and plants, elucidating the underlying mechanisms that govern NP uptake, translocation, and interactions at the cellular level. We explore how NPs influence key physiological processes and modulate plant defense responses to both biotic and abiotic stresses, highlighting their potential for enhancing stress resistance. The diverse applications of NPs in agriculture are also comprehensively surveyed, encompassing targeted delivery of nutrients, enhanced biocontrol of phytopathogens, and engineering improved tolerance to environmental extremes. We also address the broader environmental and socioeconomic implications of the widespread use of NPs in agriculture, critically evaluating their ecotoxicity, impacts on biodiversity, and the associated economic costs and benefits. Finally, we offer a perspective on future directions for research, including emerging trends in NPs synthesis and characterization, challenges to sustainable implementation, and the prospects for large-scale deployment of nanotechnology-enabled agricultural solutions. This review provides a rigorous and balanced assessment of the potential of nanotechnology to revolutionize agricultural practices while acknowledging the need for responsible innovation and risk mitigation.
Quantitative Changes in Selected Soil Health Indices as a Result of Long-Term (23-Year) Cultivation of Winter Wheat in Various Crop Rotations: Case Study for Sandy Soil
Current Trends in Sustainable Sewage Sludge Management—A Case Study for Poznań County, Poland
The formation of sewage sludge (SS) is directly related to the number of people served by municipal wastewater treatment plants (WWTPs), while it is also impacted by increasingly upgraded sewage treatment technologies used in such installations. The presence of SS in our environment raises a number of concerns regarding its proper and sustainable management. In practice, the choice of a specific SS disposal method is determined by a number of factors and, as this research has shown, it may vary significantly both on the national and regional scale. This study analyzed this phenomenon in relation to Poznań County, located in the Wielkopolskie province, Poland. As part of this study, the SS chemical composition was assessed based on data obtained directly from local municipal WWTPs over the course of several years (the last 7 years). The currently used SS management methods were analyzed in terms of SS chemical composition. Moreover, in view of the importance of public involvement in decision-making processes related to sustainable management of SS, an original survey was developed to assess local residents’ knowledge concerning SS management in Poznań County. Based on the obtained data, it was found that the generated SS, constituting a form of fertilizer, was primarily used for agricultural and reclamation purposes (over 41% of total SS mass in the case of Poznań County). It is facilitated by the chemical composition of this waste, characterized by high contents of organic matter (380–730.3 g·kg−1), nitrogen (13.3–78 g·kg−1), and calcium (9.5–350 g·kg−1), while the amounts of heavy metals were within the permissible ranges. A survey of the local community revealed that although respondents recognized and could accurately identify SS as a waste, their knowledge concerning harmfulness of this waste and its management was fragmentary. Regardless of the age of the respondents, 48 to 66% of them had no opinion concerning problems related to SS in their area. The youngest people (aged 18–25) showed the lowest level of knowledge on SS and its management. People with elementary education were the least knowledgeable about sewage sludge management. Regardless of the above, a majority of respondents (28–56% for different age groups and 7–18% for various educational backgrounds) were convinced of the validity of agricultural SS use. To sum up, research on sewage sludge is an indispensable element of activities aimed at sustainable development, combining aspects of environmental protection, circular economy, and social awareness and acceptance. Additionally, the study results indicated the need for social education to increase environmental awareness and co-responsibility for SS management.
Quantifying the impacts of spatiotemporal land use and land cover changes on soil loss across agroecologies and slope categories using GIS and RUSLE model in Zoa watershed, southwest Ethiopia
Abstract Background Soil erosion in Ethiopian highlands is highly consistent with land use/land cover (LULC) changes that are associated with deforestation and a decline in biodiversity. However, identifying soil erosion-prone areas and quantifying soil loss in rugged terrains and various agroecologies due to LULC changes have not been dedicated to scientific studies. Therefore, we quantified the impacts of spatiotemporal LULC changes on soil loss across agroecologies and slope categories using GIS and RUSLE model from 1985 to 2021 in Zoa watershed, southwest Ethiopia. Moreover, prioritizing erosion severity risks at sub-watersheds and quantifying temporal sediment yield is essential for better conservation planning. Landsat images, rainfall, Digital Elevation Model, and soil data were obtained from field observations and secondary sources. Results Bareland and farmland have been expanding at the expense of other land use types. The annual soil loss in the watershed ranged from 0 to 113.21 t ha−1 year−1, 0 to 163.16 t ha−1 year−1, and 0 to 194.58 $$\mathrm{t}\,{\mathrm{ha}}^{-1}\,{\mathrm{year}}^{-1}$$ t ha - 1 year - 1 with a mean annual soil loss of 21.07, 29.35 and 40.93 t ha−1 year−1 in 1985, 2000, and 2021, respectively. Among LULC classes, the highest soil loss was generated from bareland (31.73 $$\mathrm{t }\,{\mathrm{ha}}^{-1}\,{\mathrm{year}}^{-1}$$ t ha - 1 year - 1 ) and farmland (27.08 t ha−1 year−1 ) in 1985 later upsurged to 35.52 $$\mathrm{t }\,{\mathrm{ha}}^{-1}\,{\mathrm{year}}^{-1}$$ t ha - 1 year - 1 and 59.91 t ha−1 year−1 in 2021, respectively, due to the maximum susceptibility of soil erosion risks from unprotected surfaces. The results also revealed that the lowland agroecology generated the highest mean soil loss of 24.05 $$\mathrm{t }\,{\mathrm{ha}}^{-1}\,{\mathrm{year}}^{-1}$$ t ha - 1 year - 1 in 1985, 39.74 t ha−1 year−1 in 2000, and increased to 57.55 $$\mathrm{t }\,{\mathrm{ha}}^{-1}\,{\mathrm{year}}^{-1}$$ t ha - 1 year - 1 in 2021. Considering the slope categories, the highest and most excruciating soil loss was engendered from steep (35.55–60.78 t ha–1 year–1) and very steep (52.48–72.69 $$\mathrm{t }\,{\mathrm{ha}}^{-1}\,{\mathrm{year}}^{-1}$$ t ha - 1 year - 1 ) slope terrains during 1985–2021. The northwestern part of the watershed is the most erosion-prone area which is now expanding to the central and western parts of the watershed. The sediment yield increased at the fastest rate at the watershed outlet, from 39.3% in 1985 to 94.26% in 2021. Conclusions The results of this study indicated that the conversion of other LULC categories into farmland was the most detrimental to a watershed in terms of soil loss, which necessitates the implementation of appropriate soil and water conservation measures with effective design by considering spatial variability to reduce soil erosion hazards.
The Application of Sewage Sludge-Derived Compost or Biochar as a Nature-Based Solution (NBS) for Healthier Soil
Rate of Microelement Quantitative Changes during the Composting of Sewage Sludge with Various Bulking Agents
The composting of sewage sludge (SS) with structure-forming additives is a popular and inexpensive method for the management of biodegradable waste. During this process, a number of transformations of organic matter and nutrients occur. This study presents the rates and directions of quantitative changes in Cu, Zn, and Ni during the composting of various mixtures. The following substances were used for preparing compost mixtures: SS, sawdust, straw, and bark. These substances were mixed together in appropriate proportions as follows: C1: 45% SS + 50% sawdust + 5% straw; C2: 45% SS + 50% bark+ 5% straw; and C3: 45% SS + 35% bark + 15% sawdust + 5% straw. Single (DTPA solution) and sequential extraction methods (BCR protocol) were used for microelement mobility assessment. Compost valorization was performed in each individual composting phase. The chain relative increment analysis was used for such assessment. Additionally, the potential metal pollution in the composts was evaluated by applying the following indices: the pollutant accumulation index (PAI), heavy metal enrichment index (HMEI), and heavy metal pollution load index (HMPLI). During composting, generally, the amounts of Ni, Cu, and Zn increased in the various extracted combinations, which was independent of their susceptibility to decomposition. Despite of this, the tested composts should be considered as a source of slowly available microelements for plants. The most intense quantitative changes in metals occurred in the thermophilic phase, and the weakest changes occurred in the cooling phase. At the same time, the calculated indices indicated a lack of contamination of the composts with the analyzed metals, emphasizing their environmental safety and lack of negative impact. The bulking agents used for composting with SS did not significantly influence the intensity of the quantitative changes in the tested metals.