Effect of Variable Synthesis Conditions on the Formation of Ye’elimite-Aluminate-Calcium (YAC) Cement and Its Hydration in the Presence of Portland Cement (OPC) and Several Accessory Additives

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cris.virtual.author-orcid0000-0001-5616-3827
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cris.virtualsource.author-orcidebe065e1-88e3-4328-92a9-62cb28d0570e
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dc.abstract.enIn the presented study, ye’elimite-aluminate-calcium (YAC) cement was synthesized. Complete synthesis of crystalline phases was achieved at a temperature of 1300 °C, which is 150 °C lower than the temperature standardly used in the processes of obtaining calcium aluminate cements (CAC). The greatest amount of ye’elimite phase (Klein complex), roughly 87% by mass, was acquired utilizing a sulphur ion transporter derived from artificial dihydrate gypsum obtained in the flue gas desulphurization process (variation I). In the case of anhydrite, the amount of synthesized crystalline ye’elimite in the clinker was 67% by weight (variant II). Depending on the synthesis conditions in the clinkers, the quantity of obtained calcium aluminates (C12A7, CA, and CA2) ranged from 20 to 40% by weight. Studies on the hydration process of YAC cement samples showed that the main products are hydrated calcium aluminates and dodecahydrate calcium alumino-sulphate. In sinters of YAC and OPC, no crystalline ettringite was observed. Hydration analysis of Chinese cement revealed the presence of crystalline ettringite and dodecahydrate calcium alumino-sulphate, as well as hydrated calcium silicates of the CSH type accompanied with pseudo-crystalline Al(OH)3. The obtained clinkers from variants I and II constitute a special binder, which, due to its phase composition after hydration, can be used in the construction of reactors for biogas production in eco-energy applications.
dc.affiliationWydział Inżynierii Środowiska i Inżynierii Mechanicznej
dc.affiliation.instituteKatedra Inżynierii Biosystemów
dc.contributor.authorDurczak, Karol
dc.contributor.authorPyzalski, Michał
dc.contributor.authorBrylewski, Tomasz
dc.contributor.authorSujak, Agnieszka
dc.date.access2025-07-28
dc.date.accessioned2025-10-28T09:26:27Z
dc.date.available2025-10-28T09:26:27Z
dc.date.copyright2023-09-03
dc.date.issued2023
dc.description.abstract<jats:p>In the presented study, ye’elimite-aluminate-calcium (YAC) cement was synthesized. Complete synthesis of crystalline phases was achieved at a temperature of 1300 °C, which is 150 °C lower than the temperature standardly used in the processes of obtaining calcium aluminate cements (CAC). The greatest amount of ye’elimite phase (Klein complex), roughly 87% by mass, was acquired utilizing a sulphur ion transporter derived from artificial dihydrate gypsum obtained in the flue gas desulphurization process (variation I). In the case of anhydrite, the amount of synthesized crystalline ye’elimite in the clinker was 67% by weight (variant II). Depending on the synthesis conditions in the clinkers, the quantity of obtained calcium aluminates (C12A7, CA, and CA2) ranged from 20 to 40% by weight. Studies on the hydration process of YAC cement samples showed that the main products are hydrated calcium aluminates and dodecahydrate calcium alumino-sulphate. In sinters of YAC and OPC, no crystalline ettringite was observed. Hydration analysis of Chinese cement revealed the presence of crystalline ettringite and dodecahydrate calcium alumino-sulphate, as well as hydrated calcium silicates of the CSH type accompanied with pseudo-crystalline Al(OH)3. The obtained clinkers from variants I and II constitute a special binder, which, due to its phase composition after hydration, can be used in the construction of reactors for biogas production in eco-energy applications.</jats:p>
dc.description.accesstimeat_publication
dc.description.bibliographyil., bibliogr.
dc.description.financepublication_nocost
dc.description.financecost0,00
dc.description.if3,1
dc.description.number17
dc.description.points140
dc.description.versionfinal_published
dc.description.volume16
dc.identifier.doi10.3390/ma16176052
dc.identifier.issn1996-1944
dc.identifier.urihttps://sciencerep.up.poznan.pl/handle/item/5526
dc.identifier.weblinkhttps://www.mdpi.com/1996-1944/16/17/6052
dc.languageen
dc.relation.ispartofMaterials
dc.relation.pagesart. 6052
dc.rightsCC-BY
dc.sciencecloudnosend
dc.share.typeOPEN_JOURNAL
dc.subject.enye’elimite-aluminate cement
dc.subject.enspecial binder
dc.subject.enye’elimite
dc.subject.enspecial cement
dc.titleEffect of Variable Synthesis Conditions on the Formation of Ye’elimite-Aluminate-Calcium (YAC) Cement and Its Hydration in the Presence of Portland Cement (OPC) and Several Accessory Additives
dc.typeJournalArticle
dspace.entity.typePublication
oaire.citation.issue17
oaire.citation.volume16