Interlaboratory study of the quality of water vapor sorption data for wood from automated sorption balances

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dc.abstract.enAutomated sorption balances are widely used for characterizing the interaction of water vapor with hygroscopic materials. This paper is part of an interlaboratory study investigating the stability and performance of automated sorption balances. A previous paper in this study investigated the mass, temperature, and relative humidity (RH) stability of automated sorption balances by looking at the mass change of a non-hygroscopic sample over time. In this study, we examine the mass stability of wood samples held at constant RH for seven to ten days after a step change. The reason for the long hold times was to collect data to “operational equilibrium” where the change in mass is on the order of the inherent operational stability of the instrument. A total of 80 datasets were acquired from 21 laboratories covering absorption with final RH levels ranging from 10 to 95%. During these long hold times, several unusual behaviors were observed in the mass-vs-time curves. Deviations from expected sorption behavior were examined by fitting the data to an empirical sorption kinetics model and calculating the root mean square error (RMSE) between the observed and smoothed behavior. Samples that had a large RMSE relative to the median RMSE of the other datasets often had one of several types of errors: abrupt disturbances, diurnal oscillations, or long-term mass decline during an absorption step. In many cases, mass fluctuations were correlated with changes in the water reservoir temperature of the automated sorption balance. We discuss potential errors in sorption measurements on hygroscopic materials and suggest an acceptable level of RMSE for sorption data.
dc.affiliationWydział Leśny i Technologii Drewna
dc.affiliation.instituteKatedra Nauki o Drewnie i Techniki Cieplnej
dc.contributor.authorZelinka, Samuel L.
dc.contributor.authorGlass, Samuel V.
dc.contributor.authorFarkas, Natalia
dc.contributor.authorThybring, Emil E.
dc.contributor.authorAltgen, Michael
dc.contributor.authorRautkari, Lauri
dc.contributor.authorCurling, Simon
dc.contributor.authorCao, Jinzhen
dc.contributor.authorWang, Yujiao
dc.contributor.authorKünniger, Tina
dc.contributor.authorNyström, Gustav
dc.contributor.authorDreimol, Christopher Hubert
dc.contributor.authorBurgert, Ingo
dc.contributor.authorRoper, Mark G.
dc.contributor.authorBroom, Darren P.
dc.contributor.authorSchwarzkopf, Matthew
dc.contributor.authorYudhanto, Arief
dc.contributor.authorSubah, Mohammad
dc.contributor.authorLubineau, Gilles
dc.contributor.authorFredriksson, Maria
dc.contributor.authorOlek, Wiesław
dc.contributor.authorMajka, Jerzy
dc.contributor.authorPedersen, Nanna Bjerregaard
dc.contributor.authorBurnett, Daniel J.
dc.contributor.authorGarcia, Armando R.
dc.contributor.authorDreisbach, Frieder
dc.contributor.authorWaguespack, Louis
dc.contributor.authorSchott, Jennifer
dc.contributor.authorEsteban, Luis G.
dc.contributor.authorGarcía‑Iruela, Alberto
dc.contributor.authorColinart, Thibaut
dc.contributor.authorRémond, Romain
dc.contributor.authorMazian, Brahim
dc.contributor.authorPerré, Patrick
dc.contributor.authorEmmerich, Lukas
dc.date.access2025-09-12
dc.date.accessioned2025-09-12T11:07:55Z
dc.date.available2025-09-12T11:07:55Z
dc.date.copyright2025-04-14
dc.date.issued2025
dc.description.abstract<jats:title>Abstract</jats:title> <jats:p>Automated sorption balances are widely used for characterizing the interaction of water vapor with hygroscopic materials. This paper is part of an interlaboratory study investigating the stability and performance of automated sorption balances. A previous paper in this study investigated the mass, temperature, and relative humidity (RH) stability of automated sorption balances by looking at the mass change of a non-hygroscopic sample over time. In this study, we examine the mass stability of wood samples held at constant RH for seven to ten days after a step change. The reason for the long hold times was to collect data to “operational equilibrium” where the change in mass is on the order of the inherent operational stability of the instrument. A total of 80 datasets were acquired from 21 laboratories covering absorption with final RH levels ranging from 10 to 95%. During these long hold times, several unusual behaviors were observed in the mass-vs-time curves. Deviations from expected sorption behavior were examined by fitting the data to an empirical sorption kinetics model and calculating the root mean square error (RMSE) between the observed and smoothed behavior. Samples that had a large RMSE relative to the median RMSE of the other datasets often had one of several types of errors: abrupt disturbances, diurnal oscillations, or long-term mass decline during an absorption step. In many cases, mass fluctuations were correlated with changes in the water reservoir temperature of the automated sorption balance. We discuss potential errors in sorption measurements on hygroscopic materials and suggest an acceptable level of RMSE for sorption data.</jats:p>
dc.description.accesstimeat_publication
dc.description.bibliographyil., bibliogr.
dc.description.financepublication_nocost
dc.description.financecost0,00
dc.description.if3,1
dc.description.number4
dc.description.points70
dc.description.versionfinal_published
dc.description.volume31
dc.identifier.doi10.1007/s10450-025-00627-2
dc.identifier.eissn1572-8757
dc.identifier.issn0929-5607
dc.identifier.urihttps://sciencerep.up.poznan.pl/handle/item/4753
dc.identifier.weblinkhttps://link.springer.com/article/10.1007/s10450-025-00627-2
dc.languageen
dc.pbn.affiliationforestry
dc.relation.ispartofAdsorption
dc.relation.pagesart. 74
dc.rightsCC-BY
dc.sciencecloudsend
dc.share.typeOTHER
dc.subject.enwater vapor sorption
dc.subject.endynamic vapor sorption
dc.subject.ensorption isotherms
dc.subject.eninterlaboratory study
dc.titleInterlaboratory study of the quality of water vapor sorption data for wood from automated sorption balances
dc.typeJournalArticle
dspace.entity.typePublication
oaire.citation.issue4
oaire.citation.volume31