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  4. Mass Spectrometric Study of the Most Common Potential Migrants Extractible from the Inner Coatings of Metallic Beverage Cans
 
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Mass Spectrometric Study of the Most Common Potential Migrants Extractible from the Inner Coatings of Metallic Beverage Cans

Type
Journal article
Language
English
Date issued
2024
Author
Beszterda-Buszczak, Monika 
Kasperkowiak, Małgorzata
Teżyk, Artur
Augustynowicz, Natalia
Frański, Rafał
Faculty
Wydział Nauk o Żywności i Żywieniu
PBN discipline
food and nutrition technology
Journal
Foods
ISSN
2304-8158
DOI
10.3390/foods13132025
Web address
https://www.mdpi.com/2304-8158/13/13/2025
Volume
13
Number
13
Pages from-to
art. 2025
Abstract (EN)
Population exposure to endocrine disrupting chemical- bisphenols, which are used commonly in food containers and drinking water pipes in Europe, is above acceptable health and safety levels, according to updated research data. In order to evaluate the most abundant potential migrants in canned sweetened beverages marketed in Poland, we performed the HPLC-MS screening test of the migrants present in the can coating material. The analyzed samples represented the three top-ranked companies of the global soft drink market; it is reasonable to assume that the obtained data are of global validity. The tested can coatings and beverages contained bisphenols conjugates such as five butoxyethanol (BuOEtOH) adducts with bisphenol A diglycidyl ether (BADGE), one butoxyethanol adduct with bisphenol A monoglycidyl ether (BAMGE), and cyclo-di-BADGE. The performed HPLC-MS/MS analysis in the MRM mode enabled evaluation of the concentrations of the detected conjugates in canned beverages which were found to be very low, namely at the level of 1 µg/L. On the other hand, the high consumption of canned beverages may yield a risk associated with the presence of these compounds in the diet. The subsequent HPLC-QTOF-MS/MS experiments allowed, for the first time, a detailed determination of the fragmentation pathways of the detected migrants as well as detection of the isomers of the two migrants, namely BADGE + BuOEtOH and BADGE + BuOEtOH + HCl.
Keywords (EN)
  • canned sweetened beverages

  • can coating material

  • bisphenol A diglycidyl ether

  • butoxyethanol

  • HPLC-MS

  • fragmentation pathways

License
cc-bycc-by CC-BY - Attribution
Open access date
June 26, 2024
Project(s)
Analogi bisfenolu A oraz ich pochodne - jako nowe zanieczyszczenia żywności. Badania wstępne 
Fundusze Europejskie
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